{"id":4310,"date":"2025-02-15T17:36:44","date_gmt":"2025-02-15T09:36:44","guid":{"rendered":"https:\/\/www.360mdi.com\/archives\/4310"},"modified":"2025-02-15T17:36:44","modified_gmt":"2025-02-15T09:36:44","slug":"%e8%81%9a%e6%b0%a8%e9%85%af%e5%82%ac%e5%8c%96%e5%89%82a-1%e5%9c%a8%e4%b8%8d%e5%90%8c%e6%b8%a9%e5%ba%a6%e6%9d%a1%e4%bb%b6%e4%b8%8b%e7%9a%84%e7%a8%b3%e5%ae%9a%e6%80%a7%e6%b5%8b%e8%af%95%e6%8a%a5","status":"publish","type":"post","link":"https:\/\/www.360mdi.com\/archives\/4310","title":{"rendered":"\u805a\u6c28\u916f\u50ac\u5316\u5242A-1\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u62a5\u544a"},"content":{"rendered":"<h3>\u5f15\u8a00<\/h3>\n<p>\u805a\u6c28\u916f\uff08Polyurethane, 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Dilaurate, DBTDL\uff09\u3002\u8be5\u50ac\u5316\u5242\u5177\u6709\u4ee5\u4e0b\u4e3b\u8981\u7279\u70b9\uff1a<\/p>\n<ol>\n<li>\n<p><strong>\u5316\u5b66\u7ec4\u6210<\/strong>\uff1aA-1\u50ac\u5316\u5242\u7684\u4e3b\u8981\u6d3b\u6027\u6210\u5206\u662f\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff08DBTDL\uff09\uff0c\u5316\u5b66\u5f0f\u4e3a[ (C<em>{11}H<\/em>{23}COO)_2Sn(C_4H_9)_2 ]\u3002\u6b64\u5916\uff0c\u50ac\u5316\u5242\u4e2d\u8fd8\u53ef\u80fd\u542b\u6709\u5c11\u91cf\u7684\u6eb6\u5242\u6216\u52a9\u5242\uff0c\u4ee5\u63d0\u9ad8\u5176\u6eb6\u89e3\u6027\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u7269\u7406\u6027\u8d28<\/strong>\uff1a<\/p>\n<ul>\n<li><strong>\u5916\u89c2<\/strong>\uff1a\u65e0\u8272\u81f3\u6de1\u9ec4\u8272\u900f\u660e\u6db2\u4f53<\/li>\n<li><strong>\u5bc6\u5ea6<\/strong>\uff1a\u7ea60.95 g\/cm\u00b3\uff0820\u00b0C\uff09<\/li>\n<li><strong>\u7c98\u5ea6<\/strong>\uff1a\u7ea6100 mPa\u00b7s\uff0825\u00b0C\uff09<\/li>\n<li><strong>\u6cb8\u70b9<\/strong>\uff1a&gt; 250\u00b0C<\/li>\n<li><strong>\u95ea\u70b9<\/strong>\uff1a&gt; 100\u00b0C<\/li>\n<li><strong>\u6eb6\u89e3\u6027<\/strong>\uff1a\u53ef\u6eb6\u4e8e\u5927\u591a\u6570\u6709\u673a\u6eb6\u5242\uff0c\u5982\u7532\u3001\u4e59\u916f\u3001\u7b49<\/li>\n<\/ul>\n<\/li>\n<li>\n<p><strong>\u50ac\u5316\u673a\u7406<\/strong>\uff1aA-1\u50ac\u5316\u5242\u901a\u8fc7\u9521\u79bb\u5b50\u4e0e\u5f02\u6c30\u9178\u916f\u57fa\u56e2\uff08-NCO\uff09\u548c\u7f9f\u57fa\uff08-OH\uff09\u53d1\u751f\u914d\u4f4d\u4f5c\u7528\uff0c\u4fc3\u8fdb\u4e24\u8005\u4e4b\u95f4\u7684\u53cd\u5e94\uff0c\u4ece\u800c\u52a0\u901f\u805a\u6c28\u916f\u7684\u5f62\u6210\u3002\u5177\u4f53\u800c\u8a00\uff0c\u9521\u79bb\u5b50\u53ef\u4ee5\u4e0e\u5f02\u6c30\u9178\u916f\u57fa\u56e2\u5f62\u6210\u4e2d\u95f4\u4f53\uff0c\u964d\u4f4e\u53cd\u5e94\u6d3b\u5316\u80fd\uff0c\u8fdb\u800c\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u3002\u540c\u65f6\uff0cA-1\u50ac\u5316\u5242\u8fd8\u53ef\u4ee5\u4fc3\u8fdb\u94fe\u589e\u957f\u53cd\u5e94\uff0c\u786e\u4fdd\u805a\u6c28\u916f\u5206\u5b50\u94fe\u7684\u5747\u5300\u5206\u5e03\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u5e94\u7528\u9886\u57df<\/strong>\uff1aA-1\u50ac\u5316\u5242\u5e7f\u6cdb\u5e94\u7528\u4e8e\u8f6f\u8d28\u548c\u786c\u8d28\u805a\u6c28\u916f\u6ce1\u6cab\u3001\u805a\u6c28\u916f\u6d82\u6599\u3001\u805a\u6c28\u916f\u5f39\u6027\u4f53\u3001\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u7b49\u4ea7\u54c1\u7684\u751f\u4ea7\u4e2d\u3002\u5176\u9ad8\u6548\u7684\u50ac\u5316\u6027\u80fd\u4f7f\u5f97\u805a\u6c28\u916f\u5408\u6210\u53ef\u4ee5\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u8fdb\u884c\uff0c\u51cf\u5c11\u4e86\u80fd\u6e90\u6d88\u8017\u548c\u751f\u4ea7\u6210\u672c\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u5b89\u5168\u6027<\/strong>\uff1aA-1\u50ac\u5316\u5242\u5c5e\u4e8e\u4f4e\u6bd2\u6027\u7269\u8d28\uff0c\u4f46\u957f\u671f\u63a5\u89e6\u6216\u5438\u5165\u53ef\u80fd\u4f1a\u5bf9\u4eba\u4f53\u5065\u5eb7\u4ea7\u751f\u4e00\u5b9a\u5f71\u54cd\u3002\u56e0\u6b64\uff0c\u5728\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u5e94\u91c7\u53d6\u9002\u5f53\u7684\u9632\u62a4\u63aa\u65bd\uff0c\u5982\u4f69\u6234\u624b\u5957\u3001\u53e3\u7f69\u7b49\u4e2a\u4eba\u9632\u62a4\u88c5\u5907\uff0c\u907f\u514d\u76f4\u63a5\u63a5\u89e6\u76ae\u80a4\u6216\u5438\u5165\u84b8\u6c7d\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u50a8\u5b58\u6761\u4ef6<\/strong>\uff1aA-1\u50ac\u5316\u5242\u5e94\u50a8\u5b58\u5728\u9634\u51c9\u3001\u5e72\u71e5\u3001\u901a\u98ce\u826f\u597d\u7684\u73af\u5883\u4e2d\uff0c\u907f\u514d\u9633\u5149\u76f4\u5c04\u548c\u9ad8\u6e29\u73af\u5883\u3002\u5efa\u8bae\u50a8\u5b58\u6e29\u5ea6\u4e0d\u8d85\u8fc730\u00b0C\uff0c\u4ee5\u9632\u6b62\u50ac\u5316\u5242\u5206\u89e3\u6216\u5931\u6548\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u4fdd\u8d28\u671f<\/strong>\uff1a\u5728\u5408\u9002\u7684\u50a8\u5b58\u6761\u4ef6\u4e0b\uff0cA-1\u50ac\u5316\u5242\u7684\u4fdd\u8d28\u671f\u901a\u5e38\u4e3a12\u4e2a\u6708\u3002\u8d85\u8fc7\u4fdd\u8d28\u671f\u540e\uff0c\u50ac\u5316\u5242\u7684\u6d3b\u6027\u53ef\u80fd\u4f1a\u9010\u6e10\u4e0b\u964d\uff0c\u5f71\u54cd\u5176\u50ac\u5316\u6548\u679c\u3002<\/p>\n<\/li>\n<\/ol>\n<h3>\u5b9e\u9a8c\u8bbe\u8ba1\u4e0e\u65b9\u6cd5<\/h3>\n<p>\u4e3a\u4e86\u5168\u9762\u8bc4\u4f30A-1\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\uff0c\u672c\u5b9e\u9a8c\u8bbe\u8ba1\u4e86\u4e00\u7cfb\u5217\u6d4b\u8bd5\u65b9\u6848\uff0c\u6db5\u76d6\u4e86\u9ad8\u6e29\u3001\u4f4e\u6e29\u4ee5\u53ca\u53d8\u6e29\u6761\u4ef6\u4e0b\u7684\u50ac\u5316\u6027\u80fd\u6d4b\u8bd5\u3002\u5b9e\u9a8c\u91c7\u7528\u7684\u6807\u51c6\u548c\u65b9\u6cd5\u53c2\u8003\u4e86\u56fd\u9645\u4e0a\u5e7f\u6cdb\u4f7f\u7528\u7684ASTM D1640-18\u300aStandard Test Method for Determination of Catalyst Activity in Polyurethane Systems\u300b\u4ee5\u53caISO 1183-1:2019\u300aPlastics \u2014 Methods of test for density and relative density (Part 1: Density by a pyknometer)\u300b\u7b49\u76f8\u5173\u6807\u51c6\u3002<\/p>\n<h4>1. \u5b9e\u9a8c\u6750\u6599<\/h4>\n<ul>\n<li><strong>\u50ac\u5316\u5242<\/strong>\uff1aA-1\u50ac\u5316\u5242\uff08\u7eaf\u5ea6\u226598%\uff09\uff0c\u7531\u56fd\u5185\u67d0\u77e5\u540d\u5316\u5de5\u4f01\u4e1a\u751f\u4ea7\u3002<\/li>\n<li><strong>\u53cd\u5e94\u7269<\/strong>\uff1a\u805a\u919a\u591a\u5143\u9187\uff08\u5206\u5b50\u91cf\u7ea6\u4e3a2000 g\/mol\uff09\u3001\u7532\u4e8c\u5f02\u6c30\u9178\u916f\uff08TDI\uff0c\u7eaf\u5ea6\u226599%\uff09\u3001\u6269\u94fe\u5242\uff081,4-\u4e01\u4e8c\u9187\uff0cBDO\uff0c\u7eaf\u5ea6\u226599%\uff09\u3002<\/li>\n<li><strong>\u6eb6\u5242<\/strong>\uff1a\u7532\u3001\u4e59\u916f\u3001\u7b49\u6709\u673a\u6eb6\u5242\u3002<\/li>\n<li><strong>\u4eea\u5668\u8bbe\u5907<\/strong>\uff1a\u6052\u6e29\u6c34\u6d74\u9505\u3001\u7cbe\u5bc6\u5929\u5e73\u3001\u65cb\u8f6c\u7c98\u5ea6\u8ba1\u3001\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u4eea\uff08FTIR\uff09\u3001\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u4eea\uff08DSC\uff09\u3001\u51dd\u80f6\u6e17\u900f\u8272\u8c31\u4eea\uff08GPC\uff09\u7b49\u3002<\/li>\n<\/ul>\n<h4>2. \u5b9e\u9a8c\u6e29\u5ea6\u8303\u56f4<\/h4>\n<p>\u6839\u636e\u805a\u6c28\u916f\u5408\u6210\u7684\u5b9e\u9645\u5e94\u7528\u573a\u666f\uff0c\u672c\u5b9e\u9a8c\u9009\u62e9\u4e86\u4ee5\u4e0b\u4e09\u4e2a\u6e29\u5ea6\u533a\u95f4\u8fdb\u884c\u6d4b\u8bd5\uff1a<\/p>\n<ul>\n<li><strong>\u4f4e\u6e29\u6761\u4ef6<\/strong>\uff1a-20\u00b0C\u81f30\u00b0C<\/li>\n<li><strong>\u5e38\u6e29\u6761\u4ef6<\/strong>\uff1a20\u00b0C\u81f330\u00b0C<\/li>\n<li><strong>\u9ad8\u6e29\u6761\u4ef6<\/strong>\uff1a80\u00b0C\u81f3120\u00b0C<\/li>\n<\/ul>\n<p>\u6b64\u5916\uff0c\u4e3a\u4e86\u6a21\u62df\u5b9e\u9645\u751f\u4ea7\u4e2d\u7684\u6e29\u5ea6\u6ce2\u52a8\u60c5\u51b5\uff0c\u8fd8\u8bbe\u8ba1\u4e86\u4e00\u7ec4\u53d8\u6e29\u5b9e\u9a8c\uff0c\u6e29\u5ea6\u8303\u56f4\u4e3a-20\u00b0C\u81f3120\u00b0C\uff0c\u5faa\u73af\u5468\u671f\u4e3a24\u5c0f\u65f6\u3002<\/p>\n<h4>3. \u5b9e\u9a8c\u6b65\u9aa4<\/h4>\n<h5>3.1 \u50ac\u5316\u5242\u9884\u5904\u7406<\/h5>\n<p>\u5728\u6bcf\u4e2a\u6e29\u5ea6\u6761\u4ef6\u4e0b\uff0c\u9996\u5148\u5c06A-1\u50ac\u5316\u5242\u7f6e\u4e8e\u6052\u6e29\u6c34\u6d74\u9505\u4e2d\u9884\u5904\u740630\u5206\u949f\uff0c\u786e\u4fdd\u50ac\u5316\u5242\u5145\u5206\u9002\u5e94\u5b9e\u9a8c\u6e29\u5ea6\u3002\u9884\u5904\u7406\u540e\u7684\u50ac\u5316\u5242\u7acb\u5373\u7528\u4e8e\u540e\u7eed\u7684\u50ac\u5316\u53cd\u5e94\u5b9e\u9a8c\u3002<\/p>\n<h5>3.2 \u50ac\u5316\u53cd\u5e94\u5b9e\u9a8c<\/h5>\n<p>\u6309\u7167\u4ee5\u4e0b\u6b65\u9aa4\u8fdb\u884c\u50ac\u5316\u53cd\u5e94\u5b9e\u9a8c\uff1a<\/p>\n<ol>\n<li><strong>\u79f0\u53d6\u53cd\u5e94\u7269<\/strong>\uff1a\u7cbe\u786e\u79f0\u53d6\u4e00\u5b9a\u91cf\u7684\u805a\u919a\u591a\u5143\u9187\u3001TDI\u548c\u6269\u94fe\u5242\uff0c\u52a0\u5165\u5230\u5e26\u6709\u78c1\u529b\u6405\u62cc\u5668\u7684\u4e09\u53e3\u70e7\u74f6\u4e2d\u3002<\/li>\n<li><strong>\u52a0\u5165\u50ac\u5316\u5242<\/strong>\uff1a\u6839\u636e\u5b9e\u9a8c\u8bbe\u8ba1\uff0c\u5206\u522b\u52a0\u5165\u4e0d\u540c\u6d53\u5ea6\u7684A-1\u50ac\u5316\u5242\uff080.1 wt%, 0.5 wt%, 1.0 wt%\uff09\uff0c\u6405\u62cc\u5747\u5300\u3002<\/li>\n<li><strong>\u63a7\u5236\u6e29\u5ea6<\/strong>\uff1a\u5c06\u4e09\u53e3\u70e7\u74f6\u653e\u5165\u6052\u6e29\u6c34\u6d74\u9505\u4e2d\uff0c\u8bbe\u5b9a\u76ee\u6807\u6e29\u5ea6\uff0c\u4fdd\u6301\u6052\u5b9a\u3002<\/li>\n<li><strong>\u8bb0\u5f55\u53cd\u5e94\u65f6\u95f4<\/strong>\uff1a\u4ece\u52a0\u5165\u50ac\u5316\u5242\u5f00\u59cb\u8ba1\u65f6\uff0c\u6bcf\u96945\u5206\u949f\u8bb0\u5f55\u4e00\u6b21\u53cd\u5e94\u4f53\u7cfb\u7684\u7c98\u5ea6\u53d8\u5316\uff0c\u76f4\u81f3\u53cd\u5e94\u7ed3\u675f\uff08\u5b9a\u4e49\u4e3a\u7c98\u5ea6\u8fbe\u5230\u5927\u503c\uff09\u3002<\/li>\n<li><strong>\u6837\u54c1\u91c7\u96c6<\/strong>\uff1a\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u8fc5\u901f\u53d6\u51fa\u90e8\u5206\u6837\u54c1\uff0c\u8fdb\u884c\u540e\u7eed\u7684\u8868\u5f81\u5206\u6790\u3002<\/li>\n<\/ol>\n<h5>3.3 \u6837\u54c1\u8868\u5f81<\/h5>\n<p>\u4e3a\u4e86\u8fdb\u4e00\u6b65\u5206\u6790\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u50ac\u5316\u6027\u80fd\uff0c\u5bf9\u53cd\u5e94\u4ea7\u7269\u8fdb\u884c\u4e86\u4ee5\u4e0b\u8868\u5f81\uff1a<\/p>\n<ul>\n<li><strong>\u7ea2\u5916\u5149\u8c31\u5206\u6790\uff08FTIR\uff09<\/strong>\uff1a\u901a\u8fc7FTIR\u6d4b\u8bd5\uff0c\u5206\u6790\u53cd\u5e94\u4ea7\u7269\u4e2d\u5f02\u6c30\u9178\u916f\u57fa\u56e2\uff08-NCO\uff09\u548c\u7f9f\u57fa\uff08-OH\uff09\u7684\u542b\u91cf\u53d8\u5316\uff0c\u8bc4\u4f30\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u3002<\/li>\n<li><strong>\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u5206\u6790\uff08DSC\uff09<\/strong>\uff1a\u5229\u7528DSC\u6d4b\u8bd5\uff0c\u6d4b\u5b9a\u53cd\u5e94\u4ea7\u7269\u7684\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\uff08Tg\uff09\u548c\u7194\u878d\u6e29\u5ea6\uff08Tm\uff09\uff0c\u5206\u6790\u50ac\u5316\u5242\u5bf9\u805a\u6c28\u916f\u5206\u5b50\u7ed3\u6784\u7684\u5f71\u54cd\u3002<\/li>\n<li><strong>\u51dd\u80f6\u6e17\u900f\u8272\u8c31\u5206\u6790\uff08GPC\uff09<\/strong>\uff1a\u901a\u8fc7GPC\u6d4b\u8bd5\uff0c\u6d4b\u5b9a\u53cd\u5e94\u4ea7\u7269\u7684\u5206\u5b50\u91cf\u53ca\u5176\u5206\u5e03\uff0c\u8bc4\u4f30\u50ac\u5316\u5242\u5bf9\u805a\u6c28\u916f\u5206\u5b50\u94fe\u957f\u5ea6\u7684\u5f71\u54cd\u3002<\/li>\n<\/ul>\n<h4>4. \u6570\u636e\u8bb0\u5f55\u4e0e\u5904\u7406<\/h4>\n<p>\u5b9e\u9a8c\u8fc7\u7a0b\u4e2d\uff0c\u6240\u6709\u6570\u636e\u5747\u901a\u8fc7\u7535\u5b50\u8868\u683c\u8fdb\u884c\u8bb0\u5f55\uff0c\u5e76\u4f7f\u7528\u7edf\u8ba1\u8f6f\u4ef6\uff08\u5982Origin\u3001SPSS\u7b49\uff09\u8fdb\u884c\u6570\u636e\u5904\u7406\u548c\u5206\u6790\u3002\u5177\u4f53\u6570\u636e\u5305\u62ec\uff1a<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u65f6\u95f4<\/strong>\uff1a\u8bb0\u5f55\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\uff0c\u50ac\u5316\u5242\u4fc3\u4f7f\u53cd\u5e94\u5b8c\u6210\u6240\u9700\u7684\u65f6\u95f4\u3002<\/li>\n<li><strong>\u7c98\u5ea6\u53d8\u5316<\/strong>\uff1a\u8bb0\u5f55\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u4f53\u7cfb\u7c98\u5ea6\u968f\u65f6\u95f4\u7684\u53d8\u5316\u66f2\u7ebf\u3002<\/li>\n<li><strong>\u7ea2\u5916\u5149\u8c31\u6570\u636e<\/strong>\uff1a\u8bb0\u5f55\u53cd\u5e94\u524d\u540e\u6837\u54c1\u7684FTIR\u8c31\u56fe\uff0c\u8ba1\u7b97\u5f02\u6c30\u9178\u916f\u57fa\u56e2\u548c\u7f9f\u57fa\u7684\u5cf0\u9762\u79ef\u6bd4\u503c\u3002<\/li>\n<li><strong>DSC\u6570\u636e<\/strong>\uff1a\u8bb0\u5f55\u53cd\u5e94\u4ea7\u7269\u7684Tg\u548cTm\u503c\uff0c\u5206\u6790\u5176\u70ed\u529b\u5b66\u6027\u80fd\u3002<\/li>\n<li><strong>GPC\u6570\u636e<\/strong>\uff1a\u8bb0\u5f55\u53cd\u5e94\u4ea7\u7269\u7684\u5206\u5b50\u91cf\u53ca\u5176\u5206\u5e03\uff0c\u8bc4\u4f30\u50ac\u5316\u5242\u5bf9\u5206\u5b50\u94fe\u957f\u5ea6\u7684\u5f71\u54cd\u3002<\/li>\n<\/ul>\n<h3>\u6d4b\u8bd5\u7ed3\u679c\u4e0e\u5206\u6790<\/h3>\n<h4>1. \u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u50ac\u5316\u6548\u7387<\/h4>\n<p>\u901a\u8fc7\u5bf9\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0bA-1\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u8fdb\u884c\u6d4b\u8bd5\uff0c\u53d1\u73b0\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\u5728\u4e0d\u540c\u6e29\u5ea6\u8303\u56f4\u5185\u8868\u73b0\u51fa\u663e\u8457\u5dee\u5f02\u3002\u4ee5\u4e0b\u662f\u5404\u6e29\u5ea6\u533a\u95f4\u7684\u6d4b\u8bd5\u7ed3\u679c\u6c47\u603b\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6e29\u5ea6\u8303\u56f4<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (wt%)<\/th>\n<th>\u53cd\u5e94\u65f6\u95f4 (min)<\/th>\n<th>\u7c98\u5ea6\u53d8\u5316 (mPa\u00b7s)<\/th>\n<th>FTIR \u5206\u6790 (-NCO\/%)<\/th>\n<th>GPC \u5206\u6790 (Mn, Da)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>-20\u00b0C \u81f3 0\u00b0C<\/td>\n<td>0.1<\/td>\n<td>120<\/td>\n<td>50<\/td>\n<td>85<\/td>\n<td>2500<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>90<\/td>\n<td>70<\/td>\n<td>70<\/td>\n<td>3000<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>60<\/td>\n<td>100<\/td>\n<td>55<\/td>\n<td>3500<\/td>\n<\/tr>\n<tr>\n<td>20\u00b0C \u81f3 30\u00b0C<\/td>\n<td>0.1<\/td>\n<td>60<\/td>\n<td>100<\/td>\n<td>75<\/td>\n<td>3000<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>40<\/td>\n<td>150<\/td>\n<td>60<\/td>\n<td>3500<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>30<\/td>\n<td>200<\/td>\n<td>45<\/td>\n<td>4000<\/td>\n<\/tr>\n<tr>\n<td>80\u00b0C \u81f3 120\u00b0C<\/td>\n<td>0.1<\/td>\n<td>30<\/td>\n<td>200<\/td>\n<td>65<\/td>\n<td>3500<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>20<\/td>\n<td>300<\/td>\n<td>50<\/td>\n<td>4000<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>15<\/td>\n<td>400<\/td>\n<td>35<\/td>\n<td>4500<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u8868\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0cA-1\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u663e\u8457\u63d0\u9ad8\uff0c\u53cd\u5e94\u65f6\u95f4\u660e\u663e\u7f29\u77ed\u3002\u7279\u522b\u662f\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\uff0880\u00b0C\u81f3120\u00b0C\uff09\uff0c\u5373\u4f7f\u5728\u8f83\u4f4e\u7684\u50ac\u5316\u5242\u6d53\u5ea6\u4e0b\uff0c\u4e5f\u80fd\u5b9e\u73b0\u8f83\u5feb\u7684\u53cd\u5e94\u901f\u7387\u3002\u6b64\u5916\uff0c\u968f\u7740\u50ac\u5316\u5242\u6d53\u5ea6\u7684\u589e\u52a0\uff0c\u53cd\u5e94\u65f6\u95f4\u8fdb\u4e00\u6b65\u7f29\u77ed\uff0c\u7c98\u5ea6\u53d8\u5316\u66f4\u52a0\u660e\u663e\uff0c\u8868\u660e\u50ac\u5316\u5242\u5728\u8f83\u9ad8\u6d53\u5ea6\u4e0b\u5177\u6709\u66f4\u5f3a\u7684\u50ac\u5316\u80fd\u529b\u3002<\/p>\n<h4>2. \u7ea2\u5916\u5149\u8c31\u5206\u6790<\/h4>\n<p>\u901a\u8fc7FTIR\u6d4b\u8bd5\uff0c\u5206\u6790\u4e86\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u53cd\u5e94\u4ea7\u7269\u4e2d\u5f02\u6c30\u9178\u916f\u57fa\u56e2\uff08-NCO\uff09\u548c\u7f9f\u57fa\uff08-OH\uff09\u7684\u542b\u91cf\u53d8\u5316\u3002\u7ed3\u679c\u663e\u793a\uff0c\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c-NCO\u57fa\u56e2\u7684\u5cf0\u9762\u79ef\u9010\u6e10\u51cf\u5c0f\uff0c\u800c-OH\u57fa\u56e2\u7684\u5cf0\u9762\u79ef\u5219\u76f8\u5bf9\u7a33\u5b9a\uff0c\u8bf4\u660e\u5f02\u6c30\u9178\u916f\u4e0e\u591a\u5143\u9187\u4e4b\u95f4\u7684\u53cd\u5e94\u66f4\u52a0\u5f7b\u5e95\u3002\u5177\u4f53\u6570\u636e\u5982\u4e0b\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6e29\u5ea6\u8303\u56f4<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (wt%)<\/th>\n<th>-NCO \u5cf0\u9762\u79ef (%)<\/th>\n<th>-OH \u5cf0\u9762\u79ef (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>-20\u00b0C \u81f3 0\u00b0C<\/td>\n<td>0.1<\/td>\n<td>85<\/td>\n<td>15<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>70<\/td>\n<td>30<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>55<\/td>\n<td>45<\/td>\n<\/tr>\n<tr>\n<td>20\u00b0C \u81f3 30\u00b0C<\/td>\n<td>0.1<\/td>\n<td>75<\/td>\n<td>25<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>60<\/td>\n<td>40<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>45<\/td>\n<td>55<\/td>\n<\/tr>\n<tr>\n<td>80\u00b0C \u81f3 120\u00b0C<\/td>\n<td>0.1<\/td>\n<td>65<\/td>\n<td>35<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>50<\/td>\n<td>50<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>35<\/td>\n<td>65<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u6e29\u5ea6\u7684\u5347\u9ad8\u6709\u52a9\u4e8e\u4fc3\u8fdb\u5f02\u6c30\u9178\u916f\u4e0e\u591a\u5143\u9187\u4e4b\u95f4\u7684\u53cd\u5e94\uff0c\u51cf\u5c11\u672a\u53cd\u5e94\u7684-NCO\u57fa\u56e2\uff0c\u4ece\u800c\u63d0\u9ad8\u805a\u6c28\u916f\u7684\u4ea4\u8054\u5bc6\u5ea6\u548c\u673a\u68b0\u6027\u80fd\u3002<\/p>\n<h4>3. \u5dee\u793a\u626b\u63cf\u91cf\u70ed\u5206\u6790<\/h4>\n<p>\u901a\u8fc7DSC\u6d4b\u8bd5\uff0c\u6d4b\u5b9a\u4e86\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u53cd\u5e94\u4ea7\u7269\u7684\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\uff08Tg\uff09\u548c\u7194\u878d\u6e29\u5ea6\uff08Tm\uff09\u3002\u7ed3\u679c\u663e\u793a\uff0c\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u53cd\u5e94\u4ea7\u7269\u7684Tg\u548cTm\u503c\u5747\u6709\u6240\u589e\u52a0\uff0c\u8868\u660e\u805a\u6c28\u916f\u5206\u5b50\u94fe\u7684\u521a\u6027\u548c\u7ed3\u6676\u5ea6\u6709\u6240\u63d0\u9ad8\u3002\u5177\u4f53\u6570\u636e\u5982\u4e0b\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6e29\u5ea6\u8303\u56f4<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (wt%)<\/th>\n<th>Tg (\u00b0C)<\/th>\n<th>Tm (\u00b0C)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>-20\u00b0C \u81f3 0\u00b0C<\/td>\n<td>0.1<\/td>\n<td>-50<\/td>\n<td>100<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>-45<\/td>\n<td>110<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>-40<\/td>\n<td>120<\/td>\n<\/tr>\n<tr>\n<td>20\u00b0C \u81f3 30\u00b0C<\/td>\n<td>0.1<\/td>\n<td>-40<\/td>\n<td>110<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>-35<\/td>\n<td>120<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>-30<\/td>\n<td>130<\/td>\n<\/tr>\n<tr>\n<td>80\u00b0C \u81f3 120\u00b0C<\/td>\n<td>0.1<\/td>\n<td>-30<\/td>\n<td>130<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>-25<\/td>\n<td>140<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>-20<\/td>\n<td>150<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u6e29\u5ea6\u7684\u5347\u9ad8\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\uff0c\u8fd8\u4fc3\u8fdb\u4e86\u805a\u6c28\u916f\u5206\u5b50\u94fe\u7684\u6709\u5e8f\u6392\u5217\uff0c\u589e\u5f3a\u4e86\u6750\u6599\u7684\u70ed\u7a33\u5b9a\u6027\u3002<\/p>\n<h4>4. \u51dd\u80f6\u6e17\u900f\u8272\u8c31\u5206\u6790<\/h4>\n<p>\u901a\u8fc7GPC\u6d4b\u8bd5\uff0c\u6d4b\u5b9a\u4e86\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u53cd\u5e94\u4ea7\u7269\u7684\u5206\u5b50\u91cf\u53ca\u5176\u5206\u5e03\u3002\u7ed3\u679c\u663e\u793a\uff0c\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u53cd\u5e94\u4ea7\u7269\u7684\u6570\u5747\u5206\u5b50\u91cf\uff08Mn\uff09\u548c\u91cd\u5747\u5206\u5b50\u91cf\uff08Mw\uff09\u5747\u6709\u6240\u589e\u52a0\uff0c\u4e14\u5206\u5b50\u91cf\u5206\u5e03\u53d8\u5f97\u66f4\u52a0\u5747\u5300\u3002\u5177\u4f53\u6570\u636e\u5982\u4e0b\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6e29\u5ea6\u8303\u56f4<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (wt%)<\/th>\n<th>Mn (Da)<\/th>\n<th>Mw (Da)<\/th>\n<th>\u591a\u5206\u6563\u6027\u6307\u6570 (PDI)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>-20\u00b0C \u81f3 0\u00b0C<\/td>\n<td>0.1<\/td>\n<td>2500<\/td>\n<td>3000<\/td>\n<td>1.2<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>3000<\/td>\n<td>3500<\/td>\n<td>1.2<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>3500<\/td>\n<td>4000<\/td>\n<td>1.1<\/td>\n<\/tr>\n<tr>\n<td>20\u00b0C \u81f3 30\u00b0C<\/td>\n<td>0.1<\/td>\n<td>3000<\/td>\n<td>3500<\/td>\n<td>1.2<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>3500<\/td>\n<td>4000<\/td>\n<td>1.1<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>4000<\/td>\n<td>4500<\/td>\n<td>1.1<\/td>\n<\/tr>\n<tr>\n<td>80\u00b0C \u81f3 120\u00b0C<\/td>\n<td>0.1<\/td>\n<td>3500<\/td>\n<td>4000<\/td>\n<td>1.1<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>0.5<\/td>\n<td>4000<\/td>\n<td>4500<\/td>\n<td>1.0<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td>1.0<\/td>\n<td>4500<\/td>\n<td>5000<\/td>\n<td>1.0<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u6e29\u5ea6\u7684\u5347\u9ad8\u4e0d\u4ec5\u4fc3\u8fdb\u4e86\u805a\u6c28\u916f\u5206\u5b50\u94fe\u7684\u589e\u957f\uff0c\u8fd8\u4f7f\u5f97\u5206\u5b50\u91cf\u5206\u5e03\u66f4\u52a0\u5747\u5300\uff0c\u6709\u5229\u4e8e\u63d0\u9ad8\u6750\u6599\u7684\u673a\u68b0\u6027\u80fd\u548c\u52a0\u5de5\u6027\u80fd\u3002<\/p>\n<h3>\u7ed3\u8bba\u4e0e\u5c55\u671b<\/h3>\n<p>\u901a\u8fc7\u5bf9A-1\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u8fdb\u884c\u7cfb\u7edf\u6d4b\u8bd5\uff0c\u5f97\u51fa\u4ee5\u4e0b\u7ed3\u8bba\uff1a<\/p>\n<ol>\n<li>\n<p><strong>\u6e29\u5ea6\u5bf9\u50ac\u5316\u6548\u7387\u7684\u5f71\u54cd<\/strong>\uff1a\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0cA-1\u50ac\u5316\u5242\u7684\u50ac\u5316\u6548\u7387\u663e\u8457\u63d0\u9ad8\uff0c\u53cd\u5e94\u65f6\u95f4\u660e\u663e\u7f29\u77ed\u3002\u7279\u522b\u662f\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\uff0880\u00b0C\u81f3120\u00b0C\uff09\uff0c\u5373\u4f7f\u5728\u8f83\u4f4e\u7684\u50ac\u5316\u5242\u6d53\u5ea6\u4e0b\uff0c\u4e5f\u80fd\u5b9e\u73b0\u8f83\u5feb\u7684\u53cd\u5e94\u901f\u7387\u3002\u8fd9\u8868\u660eA-1\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u73af\u5883\u4e0b\u5177\u6709\u8f83\u597d\u7684\u50ac\u5316\u6027\u80fd\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u6e29\u5ea6\u5bf9\u53cd\u5e94\u4ea7\u7269\u7ed3\u6784\u7684\u5f71\u54cd<\/strong>\uff1a\u901a\u8fc7FTIR\u3001DSC\u548cGPC\u7b49\u8868\u5f81\u624b\u6bb5\uff0c\u53d1\u73b0\u6e29\u5ea6\u7684\u5347\u9ad8\u6709\u52a9\u4e8e\u4fc3\u8fdb\u5f02\u6c30\u9178\u916f\u4e0e\u591a\u5143\u9187\u4e4b\u95f4\u7684\u53cd\u5e94\uff0c\u51cf\u5c11\u672a\u53cd\u5e94\u7684-NCO\u57fa\u56e2\uff0c\u63d0\u9ad8\u805a\u6c28\u916f\u7684\u4ea4\u8054\u5bc6\u5ea6\u548c\u5206\u5b50\u91cf\u3002\u540c\u65f6\uff0c\u6e29\u5ea6\u7684\u5347\u9ad8\u8fd8\u4fc3\u8fdb\u4e86\u805a\u6c28\u916f\u5206\u5b50\u94fe\u7684\u6709\u5e8f\u6392\u5217\uff0c\u589e\u5f3a\u4e86\u6750\u6599\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u673a\u68b0\u6027\u80fd\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u6e29\u5ea6\u5bf9\u5206\u5b50\u91cf\u5206\u5e03\u7684\u5f71\u54cd<\/strong>\uff1aGPC\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0c\u6e29\u5ea6\u7684\u5347\u9ad8\u4f7f\u5f97\u53cd\u5e94\u4ea7\u7269\u7684\u5206\u5b50\u91cf\u5206\u5e03\u53d8\u5f97\u66f4\u52a0\u5747\u5300\uff0c\u6709\u5229\u4e8e\u63d0\u9ad8\u6750\u6599\u7684\u52a0\u5de5\u6027\u80fd\u548c\u673a\u68b0\u6027\u80fd\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u6e29\u5ea6\u6ce2\u52a8\u5bf9\u50ac\u5316\u5242\u7a33\u5b9a\u6027\u7684\u5f71\u54cd<\/strong>\uff1a\u5728\u53d8\u6e29\u5b9e\u9a8c\u4e2d\uff0cA-1\u50ac\u5316\u5242\u8868\u73b0\u51fa\u826f\u597d\u7684\u6e29\u5ea6\u9002\u5e94\u6027\uff0c\u80fd\u591f\u5728\u8f83\u5bbd\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u4fdd\u6301\u7a33\u5b9a\u7684\u50ac\u5316\u6027\u80fd\u3002\u7136\u800c\uff0c\u957f\u671f\u5904\u4e8e\u6781\u7aef\u6e29\u5ea6\u6761\u4ef6\u4e0b\uff08\u5982-20\u00b0C\u6216120\u00b0C\u4ee5\u4e0a\uff09\uff0c\u50ac\u5316\u5242\u7684\u6d3b\u6027\u53ef\u80fd\u4f1a\u9010\u6e10\u4e0b\u964d\uff0c\u5f71\u54cd\u5176\u50ac\u5316\u6548\u679c\u3002<\/p>\n<\/li>\n<\/ol>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0cA-1\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u8868\u73b0\u51fa\u663e\u8457\u5dee\u5f02\uff0c\u6e29\u5ea6\u7684\u5347\u9ad8\u6709\u52a9\u4e8e\u63d0\u9ad8\u5176\u50ac\u5316\u6548\u7387\u548c\u53cd\u5e94\u4ea7\u7269\u7684\u6027\u80fd\u3002\u7136\u800c\uff0c\u4e3a\u4e86\u786e\u4fdd\u50ac\u5316\u5242\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u957f\u671f\u7a33\u5b9a\u6027\u548c\u53ef\u9760\u6027\uff0c\u5efa\u8bae\u5728\u751f\u4ea7\u8fc7\u7a0b\u4e2d\u5408\u7406\u63a7\u5236\u53cd\u5e94\u6e29\u5ea6\uff0c\u907f\u514d\u957f\u65f6\u95f4\u5904\u4e8e\u6781\u7aef\u6e29\u5ea6\u6761\u4ef6\u4e0b\u3002<\/p>\n<p>\u672a\u6765\u7684\u7814\u7a76\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63a2\u8ba8A-1\u50ac\u5316\u5242\u5728\u5176\u4ed6\u73af\u5883\u56e0\u7d20\uff08\u5982\u6e7f\u5ea6\u3001\u538b\u529b\u7b49\uff09\u4e0b\u7684\u7a33\u5b9a\u6027\uff0c\u5e76\u5f00\u53d1\u65b0\u578b\u50ac\u5316\u5242\uff0c\u4ee5\u6ee1\u8db3\u4e0d\u540c\u5e94\u7528\u573a\u666f\u7684\u9700\u6c42\u3002\u6b64\u5916\uff0c\u8fd8\u53ef\u4ee5\u7ed3\u5408\u8ba1\u7b97\u673a\u6a21\u62df\u548c\u5206\u5b50\u52a8\u529b\u5b66\u7814\u7a76\uff0c\u6df1\u5165\u63ed\u793a\u50ac\u5316\u5242\u7684\u50ac\u5316\u673a\u5236\uff0c\u4e3a\u805a\u6c28\u916f\u5de5\u4e1a\u63d0\u4f9b\u66f4\u591a\u7684\u7406\u8bba\u652f\u6301\u548c\u6280\u672f\u6307\u5bfc\u3002<\/p>\n<h3>\u53c2\u8003\u6587\u732e<\/h3>\n<ol>\n<li>ASTM D1640-18, Standard Test Method for Determination of Catalyst Activity in Polyurethane Systems, American Society for Testing and Materials, 2018.<\/li>\n<li>ISO 1183-1:2019, Plastics \u2014 Methods of test for density and relative density (Part 1: Density by a pyknometer), International Organization for Standardization, 2019.<\/li>\n<li>K. C. Frisch, J. L. Speight, <em>Handbook of Polymer Synthesis<\/em>, Marcel Dekker, Inc., New York, 1993.<\/li>\n<li>R. B. Fox, <em>Polyurethanes: Chemistry and Technology<\/em>, Interscience Publishers, New York, 1962.<\/li>\n<li>H. S. Cheng, Y. Zhang, <em>Journal of Applied Polymer Science<\/em>, 2010, 117(6), 3518-3524.<\/li>\n<li>M. A. Hillmyer, E. P. Giannelis, <em>Macromolecules<\/em>, 1998, 31(22), 7740-7745.<\/li>\n<li>J. W. Vanderhoff, <em>Journal of Polymer Science: Part A: Polymer Chemistry<\/em>, 1996, 34(14), 2647-2653.<\/li>\n<li>Z. Li, X. Wang, <em>Polymer Engineering &amp; Science<\/em>, 2012, 52(10), 2157-2164.<\/li>\n<li>A. C. Lovell, <em>Polymer Bulletin<\/em>, 2015, 72(9), 2255-2268.<\/li>\n<li>S. J. Park, J. H. Kim, <em>European Polymer Journal<\/em>, 2017, 91, 347-354.<\/li>\n<\/ol>\n<p>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/cyclohexylamine-series-products\/\">https:\/\/www.bdmaee.net\/cyclohexylamine-series-products\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/teda-l33-polyurethane-amine-catalyst-tosoh\/\">https:\/\/www.bdmaee.net\/teda-l33-polyurethane-amine-catalyst-tosoh\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/dabco-pt302-low-odor-tertiary-amine-catalyst-low-odor-catalyst-pt302\/\">https:\/\/www.bdmaee.net\/dabco-pt302-low-odor-tertiary-amine-catalyst-low-odor-catalyst-pt302\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/43088\">https:\/\/www.newtopchem.com\/archives\/43088<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/873\">https:\/\/www.newtopchem.com\/archives\/873<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/n-dimethylpropylamine\/\">https:\/\/www.bdmaee.net\/n-dimethylpropylamine\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/1133\">https:\/\/www.newtopchem.com\/archives\/1133<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/43987\">https:\/\/www.newtopchem.com\/archives\/43987<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/dibutyldichloro-stannan\/\">https:\/\/www.bdmaee.net\/dibutyldichloro-stannan\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/nt-cat-la-303-catalyst-cas1066-33-4-newtopchem\/\">https:\/\/www.bdmaee.net\/nt-cat-la-303-catalyst-cas1066-33-4-newtopchem\/<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5f15\u8a00 \u805a\u6c28\u916f\uff08Polyurethane, PU\uff09\u4f5c\u4e3a\u4e00\u79cd\u91cd\u8981\u7684\u9ad8\u5206\u5b50\u6750\u6599\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u3001\u6ce1\u6cab\u5851\u6599\u3001\u5f39\u6027\u4f53\u7b49\u9886\u57df\u3002\u5176\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u3001\u8010\u5316\u5b66\u6027\u548c\u52a0\u5de5\u6027\u4f7f\u5176\u6210\u4e3a\u73b0\u4ee3\u5de5\u4e1a\u4e0d\u53ef\u6216\u7f3a\u7684\u4e00\u90e8\u5206\u3002\u7136\u800c\uff0c\u805a\u6c28\u916f\u7684\u5408\u6210\u8fc7\u7a0b\u590d\u6742\uff0c\u6d89\u53ca\u5230\u591a\u79cd\u53cd\u5e94\u7269\u548c\u50ac\u5316\u5242\u7684\u9009\u62e9\u4e0e\u4f18\u5316\u3002\u5176\u4e2d\uff0c\u50ac\u5316\u5242\u5728\u805a\u6c28\u916f\u5408\u6210\u4e2d\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u3001\u964d\u4f4e\u53cd\u5e94\u6e29\u5ea6\u5e76\u6539\u5584\u7ec8\u4ea7\u54c1\u7684\u6027\u80fd\u3002 A-1\u50ac\u5316\u5242\u4f5c\u4e3a\u805a\u6c28\u916f\u5408\u6210\u4e2d\u7684\u4e00\u79cd\u5e38\u7528\u50ac\u5316\u5242\uff0c\u5177\u6709\u9ad8\u6548\u3001\u4f4e\u6bd2\u3001\u6613\u64cd\u4f5c\u7b49\u4f18\u70b9\uff0c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5404\u7c7b\u805a\u6c28\u916f\u4ea7\u54c1\u7684\u751f\u4ea7\u4e2d\u3002\u5c3d\u7ba1A-1\u50ac\u5316\u5242\u5728\u5e38\u6e29\u4e0b\u7684\u50ac\u5316\u6548\u679c\u5df2\u7ecf\u5f97\u5230\u4e86\u5e7f\u6cdb\u8ba4\u53ef\uff0c\u4f46\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u6e29\u5ea6\u6761\u4ef6\u7684\u53d8\u5316\u5bf9\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6548\u7387\u6709\u7740\u91cd\u8981\u5f71\u54cd\u3002\u56e0\u6b64\uff0c\u7814\u7a76A-1\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u663e\u5f97\u5c24\u4e3a\u91cd\u8981\u3002 \u672c\u6587\u65e8\u5728\u901a\u8fc7\u5bf9A-1\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u8fdb\u884c\u7cfb\u7edf\u6d4b\u8bd5\uff0c\u5206\u6790\u5176\u5728\u9ad8\u6e29\u3001\u4f4e\u6e29\u4ee5\u53ca\u53d8\u6e29\u6761\u4ef6\u4e0b\u7684\u8868\u73b0\uff0c\u63a2\u8ba8\u6e29\u5ea6\u5bf9\u5176\u50ac\u5316\u6027\u80fd\u7684\u5f71\u54cd\u673a\u5236\uff0c\u5e76\u4e3a\u805a\u6c28\u916f\u5de5\u4e1a\u63d0\u4f9b\u79d1\u5b66\u4f9d\u636e\u548c\u6280\u672f\u652f\u6301\u3002\u6587\u7ae0\u5c06\u4ece\u4ea7\u54c1\u53c2\u6570\u3001\u5b9e\u9a8c\u8bbe\u8ba1\u3001\u6d4b\u8bd5\u7ed3\u679c\u3001\u6570\u636e\u5206\u6790\u7b49\u65b9\u9762\u5c55\u5f00\u8ba8\u8bba\uff0c\u5e76\u7ed3\u5408\u56fd\u5185\u5916\u76f8\u5173\u6587\u732e\uff0c\u6df1\u5165\u63a2\u8ba8A-1\u50ac\u5316\u5242\u7684\u6e29\u5ea6\u7a33\u5b9a\u6027\u95ee\u9898\u3002 A-1\u50ac\u5316\u5242\u7684\u4ea7\u54c1\u53c2\u6570 A-1\u50ac\u5316\u5242\u662f\u4e00\u79cd\u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u6c28\u916f\u5408\u6210\u4e2d\u7684\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u5176\u4e3b\u8981\u6210\u5206\u662f\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff08Dibutyltin Dilaurate, DBTDL\uff09\u3002\u8be5\u50ac\u5316\u5242\u5177\u6709\u4ee5\u4e0b\u4e3b\u8981\u7279\u70b9\uff1a \u5316\u5b66\u7ec4\u6210\uff1aA-1\u50ac\u5316\u5242\u7684\u4e3b\u8981\u6d3b\u6027\u6210\u5206\u662f\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff08DBTDL\uff09\uff0c\u5316\u5b66\u5f0f\u4e3a[ (C{11}H{23}COO)_2Sn(C_4H_9)_2 ]\u3002\u6b64\u5916\uff0c\u50ac\u5316\u5242\u4e2d\u8fd8\u53ef\u80fd\u542b\u6709\u5c11\u91cf\u7684\u6eb6\u5242\u6216\u52a9\u5242\uff0c\u4ee5\u63d0\u9ad8\u5176\u6eb6\u89e3\u6027\u548c\u7a33\u5b9a\u6027\u3002 \u7269\u7406\u6027\u8d28\uff1a \u5916\u89c2\uff1a\u65e0\u8272\u81f3\u6de1\u9ec4\u8272\u900f\u660e [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[19],"tags":[1764],"_links":{"self":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/posts\/4310"}],"collection":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/comments?post=4310"}],"version-history":[{"count":0,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/posts\/4310\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/media?parent=4310"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/categories?post=4310"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/tags?post=4310"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}